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Checking Equilibrium With an Added Inert Gas 4 questions

Checking Equilibrium With an Added Inert Gas

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A model gas reaction is A ⇌ 2 B. It is initially at equilibrium at fixed temperature. A chamber contains six A and six B particle units in volume three. In the model each gas’s pressure contribution equals its count divided by volume. A separate inert gas does not react.

After adding the inert gas, rigid chamber P has volume three and movable-piston chamber Q has volume four. Both contain six A, six B, and four inert particle units.
Chambers just after inert gas enters, before A and B respond.
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Question 1

Which trial keeps both reactive pressure contributions at their original values just after the addition?

  1. P only
  2. Q only
  3. Both trials
  4. Neither trial

Question 2

Find the total pressure just after adding inert gas in each trial. Include the inert contribution.

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In the display, adding inert gas at fixed volume leaves the original equilibrium unchanged. A volume increase favors the side with more gas particles until a new equilibrium is reached.

Question 3

Predict which trial changes its A-to-B composition as it settles and which side it favors.

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Question 4

A student says the larger change in total pressure marks the trial with a composition shift. Evaluate the claim with the two trials.

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