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Checking Oxygen in a Sulfite Conversion Model 4 questions

Checking Oxygen in a Sulfite Conversion Model

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A class models dissolved sulfite, SO32-, changing to sulfate, SO42-, when oxygen is present. It uses the balanced model equation and assigns oxygen an oxidation number of −2 in both ions. In O2 the oxidation number is 0.

2SO32-(aq) + O2(g) → 2SO42-(aq)

Question 1

Calculate sulfur’s oxidation number in each ion. Show how the ion charge enters the calculation.

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Question 2

Which description follows from the sulfur change?

  1. Sulfur is oxidized because its oxidation number increases.
  2. Sulfur is reduced because its oxidation number increases.
  3. Sulfur is oxidized because its oxidation number decreases.
  4. Sulfur has no change in oxidation number.

A student claims oxygen cannot be reduced in this reaction because the sulfate ion has the same overall charge as sulfite.

Question 3

Use the oxidation numbers of oxygen in O₂ and in sulfate to evaluate the claim.

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Question 4

How many electrons are accounted for by the oxidation of the two sulfur atoms in the equation? Explain why the two oxygen atoms from O₂ can account for the same total.

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